I've found the LO is SUPER cranky for DH if I wake him up to feed. So I will only nurse LO in the AM if he wakes up on his own, otherwise I will just pump and leave it for DH.
DD is sleeping when I wake up in the morning. I pump first thing, then shower and get myself ready. If she wakes up while I am getting ready, I will feed her. Most often though, she just stays sleeping, so I pump for her for the day.
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Re: Working / BF moms...
I would probably wake up LO before I left because my LO is STTN so I feed him and then pump the other side. That's how it works for me.