How did you learn? Take a class? Read a book? It just doesn't seem to be very intuitive. Usually I just go to picasa and pick "I'm feeling lucky" and then adjust it if it doesn't seem right. Luckily since I use my dad's canon 5D my pics don't need much adjustment unless it's weird lighting, but I'd still like to know how to use it.
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Re: photoshop users
I read tons and tons and tons of online tutorials and just played around, figuring out what the different tools could do. I thought about checking out a book at the library but found that photography blogs (found just by searching Google) provide amazing and free information, much of the time.
I shoot in RAW mode so that I can use the RAW editor on Photoshop, which saves me a million steps later. I recommend trying that. It seems overwhelming at first and the files are, ummm, GIANT but I love that quality.
Using actions is helpful, too. I don't always run actions but they're handy when you want to give a photo a certain effect or different look. Plus, the black and white in action sets blow any b&w I can create out of the water.
Have you tried Coffee shops Vanilla bw action. I think that's what it's called. I love it so much more than most bw actions becuase it doesn't blow out the whites.
I love it with every ounce of my being.
For real.